You can use Skype API which I will say a bulky way. Here is a simple method:

System.Diagnostics.Process.Start("callto:+919846089033");

It does not need to be a phone number. It can be a Skype name also.

System.Diagnostics.Process.Start("callto:ninethsense");

Note that this is not only for Skype but this callto:// will invoke any associated default calling program. It can beNet Meeting also.

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